We measure the dispersion of the Cu-O bond-stretching phonon mode in the high-temperature superconducting parent compound
Ca
2
CuO
2
Cl
2
. Our density functional theory calculations predict a cosine-shaped bending of the dispersion along both the
(
ξ
00
) and
(
ξ
ξ
0
) directions, while comparison with previous results on
Ca
1.84
CuO
2
Cl
2
show it only along
(
ξ
00
), suggesting an anisotropic effect which is not reproduced in calculation. Comparison with isostructural
La
2
−
x
Sr
x
CuO
4
and literature suggests that these calculations reproduce well the dispersion in the overdoped regime.
【論文】Doping-induced in-plane anisotropy of bond-stretching phonon softening in oxychloride Ca2−xCuO2Cl2 compounds
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フロンティア材料研究所 東正樹教授とMatteo d’Astuto特任准教授の共著論文がPHYSICAL REVIEWに掲載されました。
“Doping-induced in-plane anisotropy of bond-stretching phonon softening in oxychloride Ca2−xCuO2Cl2 compounds “
(DOI:10.1103/PhysRevB.101.020506 )
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