社会実装研究
Satoru Tsushima 津島 悟
特任准教授
計算化学 錯体化学 分子動力学 分光学
研究プロジェクト
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量子化学計算を用いたアクチノイド錯体化学および分光学
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高温環境下における水溶液系アクチノイド化学および熱力学
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フラグメント分子軌道計算を用いた生体高分子と金属イオンの相互作用
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Interaction of uranyl and peptides
Project summary: Computational modeling of engineered peptides that can selectively bind uranium. The idea of the project is to model such peptides computationally and to experimentally prove their high selectivity.
Periods: April 2019 – March 2022
Members: Satoru Tsushima (PI), Koichiro Takaouranyl ion peptide DFT NMR
トピックス
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ドイツ新聞Die Welt誌上にて”The role of water H-bond imbalances in B-DNA substate transitions and peptide recognition revealed by time-resolved FTIR spectroscopy” (J. Am. Chem. Soc. 2011, 133(15), 5834-5842)が紹介されました。
| 2017- |
東京工業大学科学技術創成研究院 特任准教授 |
|---|---|
| 2006- |
Helmholtz-Zentrum Dresden Rossendorf 上席研究員 |
| 2005-2006 |
ストックホルム大学物理工学科 客員教授 |
| 2003-2005 |
名古屋大学大学院 助教授 |
| 1999-2003 |
東京大学大学院 助手 |
| 2005 |
Waste Management Symposia 2004 Best Poster Award: Nuclear Engineering Divition of the American Society of Mechanical Engineers (ASME) (2005.2) |
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| 2003 |
Promising Endeavor Award: Atomic Energy Society of Japan, (2003.3) |
| 2020 |
Koichiro Takao, Juliane März, Moe Matsuoka, Takanori Mashita, Hiroyuki Kazama, Satoru Tsushima. “Crystallization of colourless hexanitratoneptunate(iv) with anhydrous H+ countercations trapped in a hydrogen bonded polymer with diamide linkers” RSC Adv., 2020, 10, 6082-6087. |
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| 2020 |
Tsubasa Inoue, Hiroyuki Kazama, Satoru Tsushima, and Koichiro Takao. “Essential Role of Heterocyclic Structure of N-Alkylated 2-Pyrrolidone Derivatives for Recycling Uranium from Spent Nuclear Fuels” Bull. Chem. Soc. Jpn. 2020, 93, 846-853. |
| 2020 |
Jerome Kretzschmar, Satoru Tsushima, Bjorn Drobot, Robin Steudtner, Katja Schmeide and Thorsten Stumpf. “Trimeric uranyl(VI)–citrate forms Na+, Ca2+, and La3+ sandwich complexes in aqueous solution” Chem. Commun., 2020, 56, 13133-13136. |
| 2019 |
Andre Rossberg, Takaya Abe, Koji Okuwaki, Astrid Barkleit, Kaori Fukuzawa, Tatsuya Nakano, Yuji Mochizuki and Satoru Tsushima. “Destabilization of DNA through interstrand crosslinking by UO2 2+” Chem. Commun., 2019, 55, 2015-2018. |
| 2019 |
Mashita, T.; Tsushima, S.; Takao, K. “Photocatalytic Oxygenation of Cyclohexene Initiated by Excitation of [UO2(OPCyPh2)4]2+ under Visible Light” ACS Omega, 2019, 4, 7194–7199. |
| 2019 |
Hiroyuki Kazama, Satoru Tsushima, Koichiro Takao. “Crystallization of Anhydrous Proton from Acidic Aqueous Solution with Diamide Building Block” Cryst. Growth Des. 2019 , 19 , 11 , 6048–6052. |
| 2019 |
Katharina Müller, Harald Foerstendorf , Robin Steudtner, Satoru Tsushima , Michael U. Kumke, Grégory Lefèvre, Jörg Rothe, Harris Mason , Zoltán Szabó, Ping Yang , Christian K. R. Adam , Rémi André, Katlen Brennenstuhl, Ion Chiorescu, Herman M. Cho , Gaëlle Creff, Frédéric Coppin, Kathy Dardenne, Christophe Den Auwer , Björn Drobot , Sascha Eidner, Nancy J. Hess, Peter Kaden, Alena Kremleva, Jerome Kretzschmar, Sven Krüger, James A. Platts, Petra J. Panak, Robert Polly, Brian A. Powell, Thomas Rabung, Roland Redon, Pascal E. Reiller, Notker Rösch, André Rossberg, Andreas C. Scheinost, Bernd Schimmelpfennig, Georg Schreckenbach, Andrej Skerencak-Frech, Vladimir Sladkov, Pier Lorenzo Solari, Zheming Wang, Nancy M. Washton, and Xiaobin Zhang. “Interdisciplinary Round-Robin Test on Molecular Spectroscopy of the U(VI) Acetate System” ACS Omega 2019, 4, 8167−8177. |
| 2019 |
Rohan Jain, Siyuan Fan, Peter Kaden, Satoru Tsushima, Harald Foerstendorf ,Robert Barthen, Falk Lehmann, Katrin Pollmann. “Recovery of gallium from wafer fabrication industry wastewaters by Desferrioxamine B and E using reversed-phase chromatography approach” Water Research Volume 158, 1 July 2019, Pages 203-212 |
| 2019 |
Bjorn Drobot, Moritz Schmidt, Yuji Mochizuki, Takaya Abe, Koji Okuwaki, Florian Brulfert, Sven Falke, Sergey A. Samsonov, Yuto Komeiji, Christian Betzel, Thorsten Stumpf,Johannes Raff and Satoru Tsushima. “Cm3+/Eu3+ induced structural, mechanistic and functional implications for calmodulin” Phys.Chem.Chem.Phys.,2019, 21, 21213 |
| 2019 |
Satoru Tsushima. “Lanthanide-induced conformational change of methanol dehydrogenase involving coordination change of cofactor pyrroloquinoline quinone” Phys.Chem.Chem.Phys.,2019, 21, 21979 |
| 2018 |
Takao, K.; Kazama, H.; Ikeda, Y.; Tsushima, S. “Crystal Structure of Regularly Th -Symmetric [U(NO3)6]2- Salts with Hydrogen Bond Polymers of Diamide Building Blocks” Angew. Chem. Int. Ed., 2019, 58, 240-243. |
| 2018 |
Takanori Mashita, Satoru Tsushima and Koichiro Takao ”Controlling the lability of uranyl(VI) through intramolecular π–π stacking” Dalton Transactions., 2018, 47, 13072-13080. |
| 2018 |
Toni Haubitz, Satoru Tsushima, Robin Steudtner,Björn Drobot, Gerhard Geipel, Thorsten Stumpf, and Michael U. Kumke “Ultrafast Transient Absorption Spectroscopy of UO2 2+ and [UO2Cl]+” J. Phys. Chem. A 2018,122, 6970−6977.
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| 2018 |
K.Takao, S.Tsushima “The oxidation of borohydrides by photoexcioted [UO2(CO3)3]4- ”, Dalton Trans. 2018, 47 (15), 5149-5152. |
| 2017 |
H.Kazama, S.Tsushima, Y.Ikeda, K.Takao, “Molecular and Crystal Structures of Uranyl Nitrate Coordination Polymers with Double-Headed 2‑Pyrrolidone Derivatives” Inorg. Chem. 2017, 56(21), 13530–13534. |